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International Academy of Wood Science 2018 Annual Meeting

Papers Proceedings »

MECHANICAL CHARACTERIZATION OF GLICIDYL METHACRYLATE-COMPATIBILIZED POLYLACTIC ACID/NATURAL FIBERS BIOCOMPOSITES

The use of biodegradable polymers has increased significantly in the last years. The polylactic acid (PLA) is the most used biopolymer due to its wide range of commercial grades, easy processability and interesting properties. Nevertheless, the PLA has some disadvantages such as high brittleness, low flexural strength and higher cost than other conventional polymers. These PLA drawbacks can be overcome combining the PLA with reinforcements such as inorganic or organic fibers to produce biocomposites. Natural fiber reinforced polymers have shown substantial increase of interest in the recent years. Natural fibers offer good opportunities as reinforcement for composites like biodegradability, low cost, and good mechanical properties. However, the different polar character of the natural fibers and PLA produces an incompatible interphase that sometimes results in low mechanical properties. In this sense, a coupling agent was prepared by reactive extrusion with glicidyl methacrylate (GMA) and PLA using dicumyl peroxide as initiator. The GMA-g-PLA (10 wt%) was used to produce compatibilized PLA/agave fiber bicomposites (60/30 wt%) by extrusion followed by injection molding. The mechanical (flexural, tensile and impact) and thermal properties of compatibilized and uncompatibilized biocomposites were evaluated. The results showed that fiber addition to PLA decreases tensile (from 56 to 51 MPa) and flexural strength (from 86 to 72 MPa), while with the GMA-g-PLA inclusion these properties increased (66 MPa to tensile strength and 104 MPa to flexural strength). Additionally, flexural and tensile modulus of PLA also increased with the addition of agave fiber and GMA-g-PLA.

ALAN SALVADOR MARTÍN DEL CAMPO FLORES
UNIVERSIDAD DE GUADALAJARA
Mexico

MARTÍN ARELLANO
UNIVERSIDAD DE GUADALAJARA
Mexico

JORGE RAMÓN ROBLEDO ORTIZ
UNIVERSIDAD DE GUADALAJARA
Mexico

EDGAR JOSÉ LÓPEZ NARANJO
UNIVERSIDAD DE GUADALAJARA
Mexico

AIDA ALEJANDRA PEREZ FONSECA
UNIVERSIDAD DE GUADALAJARA
Mexico

 


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